Dabrowska et al., 2013

We present measurements of the complete scattering matrix as a function of the scattering angle of a sample of calcite particles. The measurements are performed at 647 nm in the scattering angle range from 3º to 177º. To facilitate the use of the experimental data we present a synthetic scattering matrix based on the measurements and defined in the full range from 0º to 180º. The scattering matrix of the calcite sample is modeled using the discrete-dipole approximation. Two sets of shapes, flake-like and rhomboid-like particles giving a total of 15 different targets are considered since both types of shapes have been found in our calcite sample. In our computations we use the measured size distribution of the calcite sample truncated at 1.2 mm. We present a theoretical study of the impact of birefringence on the computed scattering matrix elements for both sets of shapes. Four different cases regarding the composition of the calcite particles are considered: two isotropic cases corresponding to the ordinary and extraordinary refractive index of calcite, respectively; one equivalent isotropic case analogous to internal mixing; and birefringence fully accounted for. Numerical simulations are compared with the experimental data. We find that birefringence has little impact on the calculated phase functions but it has a significant effect on the polarization-related elements of the scattering matrix. Moreover, we conclude that the shape of the targets (flakes or irregular rhomboids) has a much stronger effect on the computed scattering matrix elements than birefringence.